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991.
David Santiago Xavier Fernández‐Francos Francesc Ferrando Silvia De la Flor 《Journal of Polymer Science.Polymer Physics》2015,53(13):924-933
A series of shape‐memory epoxy thermosets were synthesized by crosslinking diglycidyl ether of bisphenol A with mixtures of commercially available hyperbranched poly(ethyleneimine) and polyetheramine. Thermal, mechanical and shape‐memory properties were studied and the effect on them of the content and structure of the hyperbranched polymer was discussed. Measurements showed that the glass transition temperature can be tailored from 60 °C to 117 °C depending on the hyperbranched polymer content, and all formulations showed an appropriate glassy/rubbery storage modulus ratio. Shape‐memory programming was carried out at TgE′ given the excellent mechanical properties of the materials, with maximum stress and failure strain up to 15 MPa and 60%, respectively. The resulting shape‐memory behavior was excellent, with maximum shape recovery and shape fixity of 98% as well as a fast shape‐recovery rate of 22%/min. The results show that hyperbranched poly(ethyleneimine) as a crosslinking agent can be used to enhance mechanical and shape‐memory properties with different effects depending on the crosslinking density. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2015 , 53, 924–933 相似文献
992.
Sebastian Werner Clarissa Glaser Thomas Kasper Trung Nghia Nguyên Lê Prof. Dr. Silvia Gross Prof. Dr. Bernd M. Smarsly 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(3):e202103437
The precise detection of the toxic gas H2S requires reliable sensitivity and specificity of sensors even at minute concentrations of as low as 10 ppm, the value corresponding to typical exposure limits. CuO can be used for H2S dosimetry, based on the formation of conductive CuS and the concomitant significant increase in conductance. In theory, at elevated temperature the reaction is reversed and CuO is formed, ideally enabling repeated and long-term use of one sensor. Yet, the performance of CuO tends to drop upon cycling. Utilizing defined CuO nanorods we thoroughly elucidated the associated detrimental chemical changes directly on the sensors, by Raman and electron microscopy analysis of each step during sensing (CuO→CuS) and regeneration (CuS→CuO) cycles. We find the decrease in the sensing performance is mainly caused by the irreversible formation of CuSO4 during regeneration. The findings allowed us to develop strategies to reduce CuSO4 formation and thus to substantially maintain the sensing stability even for repeated cycles. We achieved CuO-based dosimeters possessing a response time of a few minutes only, even for 10 ppm H2S, and prolonged life-time. 相似文献
993.
Dr. Denise Lovison Dr. Dario Alessi Dr. Lorenzo Allegri Dr. Federica Baldan Dr. Maurizio Ballico Prof. Giuseppe Damante Dr. Marilisa Galasso Prof. Daniele Guardavaccaro Dr. Silvia Ruggieri Prof. Andrea Melchior Dr. Daniele Veclani Dr. Chiara Nardon Prof. Walter Baratta 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(33):e202200200
The chiral cationic complex [Ru(η1-OAc)(CO)((R,R)-Skewphos)(phen)]OAc ( 2 R ), isolated from reaction of [Ru(η1-OAc)(η2-OAc)(R,R)-Skewphos)(CO)] ( 1 R ) with phen, reacts with NaOPiv and KSAc affording [RuX(CO)((R,R)-Skewphos)(phen)]Y (X=Y=OPiv 3 R ; X=SAc, Y=OAc 4 R ). The corresponding enantiomers 2 S - 4 S have been obtained from 1 S containing (S,S)-Skewphos. Reaction of 2 R and 2 S with (S)-cysteine and NaPF6 at pH=9 gives the diastereoisomers [Ru((S)-Cys)(CO)(PP)(phen)]PF6 (PP=(R,R)-Skewphos 2 R -Cys; (S,S)-Skewphos 2 S -Cys). The DFT energetic profile for 2 R with (S)-cysteine in H2O indicates that aquo and hydroxo species are involved in formation of 2 R -Cys. The stability of the ruthenium complexes in 0.9 % w/v NaCl solution, PBS and complete DMEM medium, as well as their n-octanol/water partition coefficient (logP), have been evaluated. The chiral complexes show high cytotoxic activity against SW1736, 8505 C, HCT-116 and A549 cell lines with EC50 values of 2.8–0.04 μM. The (R,R)-Skewphos derivatives show higher cytotoxicity compared to their enantiomers, 4 R (EC50=0.04 μM) being 14 times more cytotoxic than 4 S against the anaplastic thyroid cancer 8505 C cell line. 相似文献
994.
995.
We study minimum degree conditions for which a graph with given odd girth has a simple structure. For example, the classical work of Andrásfai, Erd?s, and Sós implies that every n‐vertex graph with odd girth and minimum degree bigger than must be bipartite. We consider graphs with a weaker condition on the minimum degree. Generalizing results of Häggkvist and of Häggkvist and Jin for the cases and 3, we show that every n‐vertex graph with odd girth and minimum degree bigger than is homomorphic to the cycle of length . This is best possible in the sense that there are graphs with minimum degree and odd girth that are not homomorphic to the cycle of length . Similar results were obtained by Brandt and Ribe‐Baumann. 相似文献
996.
Lidia Caporossi Giovanna Tranfo Enrico Paci Mariangela De Rosa Silvia Capanna Felice Tidei Bruno Papaleo 《Chromatographia》2010,72(3-4):281-287
An LC–DAD method was developed to determine residues of oxamyl on greenhouse workers’ skin. The wipe test was used to obtain samples from hands, forearms, neck and gloves of workers taking cactus cuttings 48 h after pesticide treatment. It was validated in a concentration range 50–5,000 ng mL?1. The results on six workers and ten office employees indicated significant differences particularly in the hand samples. To avoid the overestimation owing to an interfering substance we proceeded to confirm these findings with LC–MS–MS, which found the pesticide only on the surface of the workers’ gloves, proving that there was indeed some UV interference. 相似文献
997.
Silvia Kováčová Lucia Kováčiková Margita Lácová Andrej Boháč Marta Sališová 《Chemical Papers》2010,64(6):806-811
Perkin condensation with subsequent intramolecular lactonisation as one pot syntheses of 2-(2-oxo-2H-chromen-3-yl)acetic acids VIIa-Xa has been studied. The required acids VIIa-Xa were prepared as precursors of recently discovered compounds possessing antineoplastic activities. Syntheses of VIIa-Xa were carried out using para substituted 2-hydroxybenzaldehydes II-VI, succinic acid anhydride, sodium succinate under thermal or microwave conditions. Significant shortening of the reaction
time under microwave irradiation was observed (18–50 min instead of 1.5–5 h of heating). Microwave assisted reactions proceeded
more smoothly to give higher yield of the required products VIIa-Xa (31–61 %) compared to those under classical thermal conditions e.g. 21.8 % for IXa (Hurenkamp et al., 2007). Seven reaction by-products were isolated and determined as 2H,2′H-3,3′-bichromene-2,2′-diones VIIb-Xb and (E)-3-(2-hydroxystyryl)-2H-chromen-2-ones VIIc-IXc. 相似文献
998.
Boros Borbla Farkas gnes Jakabov Silvia Bacskay Ivett Kilr Ferenc Felinger Attila 《Chromatographia》2010,71(1):43-49
The present study aimed at determining selected alkaloid components in the nectar of Datura species, to elucidate whether the alkaloid content of the floral nectar can lead to intoxication. A simple and rapid liquid chromatography coupled with electrospray mass spectrometry analysis was developed for the quantitative determination of atropine and scopolamine, the main toxic alkaloids of the Datura species. This method allowed the direct coupling of an electrospray mass selective detector to the LC system. Under these conditions, atropine and scopolamine were well separated from other components and detected with mass spectrometry (mass selective detector). Simultaneous determination of atropine and scopolamine was performed with gradient elution on an Ascentis Express C18 (Supelco) reversed-phase column based on a new fused core particle design. Liquid chromatography coupled with electrospray mass spectrometry was used in positive ion mode. Atropine and scopolamine produced protonated species at m/z 290 and 304 (which are also the base peaks). Our data confirmed that the alkaloid characteristics for the vegetative and reproductive parts of the Datura plants may also occur in the nectar secreted by the flowers. In Datura species with large flowers and high nectar amounts, the alkaloid content increases proportionately and thus the nectar may be a potential source of intoxication. 相似文献
999.
A unique and practical synthetic sequence for rapid access to polyketides and to further the spiroacetals derived from them, which utilizes a bidirectional Hosomi-Sakurai allylation approach around key allylsilanes in the synthesis of the AB and CD ring systems of spongistatin 1 and 2, is reported. The synthesis of the AB spiroacetal 9 requires 13 steps, with a longest linear sequence of seven steps in an overall yield of 27%. The synthesis of the CD spiroacetal 13 requires 15 steps, with a longest linear sequence of 11 steps in an overall yield of 30%. Both syntheses start from but-3-enol. 相似文献
1000.